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71.
Multibeam bathymetry, high (sleeve airguns) and very high resolution (parametric system-TOPAS-) seismic records were used to define the morphosedimentary features and investigate the depositional architecture of the Cantabrian continental margin. The outer shelf (down to 180–245 m water depth) displays an intensively eroded seafloor surface that truncates consolidated ancient folded and fractured deposits. Recent deposits are only locally present as lowstand shelf-margin deposits and a transparent drape with bedforms. The continental slope is affected by sedimentary processes that have combined to create the morphosedimentary features seen today. The upper (down to 2000 m water depth) and lower (down to 3700–4600 m water depth) slopes are mostly subject to different types of slope failures, such as slides, mass-transport deposits (a mix of slumping and mass-flows), and turbidity currents. The upper slope is also subject to the action of bottom currents (the Mediterranean Water — MW) that interact with the Le Danois Bank favouring the reworking of the sediment and the sculpting of a contourite system. The continental rise is a bypass region of debris flows and turbidity currents where a complex channel-lobe transition zone (CLTZ) of the Cap Ferret Fan develops.The recent architecture depositional model is complex and results from the remaining structural template and the great variability of interconnected sedimentary systems and processes. This margin can be considered as starved due to the great sediment evacuation over a relatively steep entire depositional profile. Sediment is eroded mostly from the Cantabrian and also the Pyrenees mountains (source) and transported by small stream/river mountains to the sea. It bypasses the continental shelf and when sediment arrives at the slope it is transported through a major submarine drainage system (large submarine valleys and mass-movement processes) down to the continental rise and adjacent Biscay Abyssal Plain (sink). Factors controlling this architecture are tectonism and sediment source/dispersal, which are closely interrelated, whereas sea-level changes and oceanography have played a minor role (on a long-term scale).  相似文献   
72.
73.
Identifying regions sensitive to external radiative changes, including anthropogenic (sulphate aerosols and greenhouse gases) and natural (volcanoes and solar variations) forcings, is important to formulate actionable information at multi-year time-scales. Internally-generated climate variability can overcome this radiative forcing, especially at regional level, so that detecting the areas for this potential dominance is likewise critical for decadal prediction. This work aims to clarify where each contribution has the largest effect on North Atlantic sea surface temperature (SST) predictions in relation to the Atlantic multi-decadal variability (AMV). Initialized decadal hindcasts and radiatively-forced historical simulations from the fifth phase of the Climate Model Intercomparison Project are analysed to assess multi-year skill of the AMV. The initialized hindcasts reproduce better the phase of the AMV index fluctuations. The radiatively-forced component consists of a residual positive trend, although its identification is ambiguous. Initialization reduces the inter-model spread when estimating the level of AMV skill, thus reducing its uncertainty. Our results show a skilful performance of the initialized hindcasts in capturing the AMV-related SST anomalies over the subpolar gyre and Labrador Sea regions, as well as in the eastern subtropical basin, and the inability of the radiatively-forced historical runs to simulate the horseshoe-like AMV signature over the North Atlantic. Initialization outperforms empirical predictions based on persistence beyond 1–4 years ahead, suggesting that ocean dynamics play a role in the AMV predictability beyond the thermal inertia. The initialized hindcasts are also more skilful at reproducing the observed AMV teleconnection to the West African monsoon. The impact of the start date frequency is also described, showing that the standard of 5-year interval between start dates yields the main features of the AMV skill that are robustly detected in hindcasts with yearly start date sampling. This work updates previous studies, complementing them, and concludes that skilful initialized multi-model forecasts of the AMV-related climate variability can be formulated, improving uninitialized projections, until 3–6 years ahead.  相似文献   
74.
Abstract– Six large iron meteorites have been discovered in the Meridiani Planum region of Mars by the Mars Exploration Rover Opportunity in a nearly 25 km‐long traverse. Herein, we review and synthesize the available data to propose that the discovery and characteristics of the six meteorites could be explained as the result of their impact into a soft and wet surface, sometime during the Noachian or the Hesperian, subsequently to be exposed at the Martian surface through differential erosion. As recorded by its sediments and chemical deposits, Meridiani has been interpreted to have undergone a watery past, including a shallow sea, a playa, an environment of fluctuating ground water, and/or an icy landscape. Meteorites could have been encased upon impact and/or subsequently buried, and kept underground for a long time, shielded from the atmosphere. The meteorites apparently underwent significant chemical weathering due to aqueous alteration, as indicated by cavernous features that suggest differential acidic corrosion removing less resistant material and softer inclusions. During the Amazonian, the almost complete disappearance of surface water and desiccation of the landscape, followed by induration of the sediments and subsequent differential erosion and degradation of Meridiani sediments, including at least 10–80 m of deflation in the last 3–3.5 Gy, would have exposed the buried meteorites. We conclude that the iron meteorites support the hypothesis that Mars once had a denser atmosphere and considerable amounts of water and/or water ice at and/or near the surface.  相似文献   
75.
Polycyclic aromatic hydrocarbons (PAHs) were measured in the coastal sea surface microlayer (SML), the sub-surface waters (SSW) and the overlying atmosphere in order to investigate the influence of the SML on contaminant enrichment and air-sea exchange. Samples were collected at two contrasting locations of the NW Mediterranean, one urban influenced (off Barcelona, Spain) and another comparatively clean (off Banyuls-sur-Mer, France). Statistical data analysis confirmed the accumulation of PAHs in the SML with respect to the SSW (20.3+/-9.1 vs. 13.1+/-10.0 ng L(-1) in the dissolved phase; 709+/-207 vs. 158+/-111 ng g(-1) in the particulate phase). This accumulation was higher at the contaminated location (Barcelona station) compared with the more pristine one, with PAH enrichments 1.5 and 4.5 times higher for the dissolved and particulate phases, respectively, indicating that the enrichment of PAHs in the SML is dominated by particle transport processes.  相似文献   
76.
An investigation on the effects of deepwater outfall discharges on the status of rocky reef communities was carried out. The sanitation system was found to be an environmentally suitable option for the protection of those habitats situated in high energy coastal environments. Sediments occurring between the predominating rocky substrates showed low values of the fine fraction (<63microm) and organic matter content. In addition, high average concentrations of Cd, Hg and Zn were found in these sediments, though these values were similar to those registered in non-affected sites, far away from the outfall. On the other hand, those assemblages typical of hard substrates that settled near the outfall showed an increase in total richness and abundance of macroinvertebrates. Moreover, the average number of species of each taxonomic group, a good indicator of the maintenance of the previous trophic structure, only varied considerably over time at the rip-rap protection. In a global context, those changes were not directly related to the discharge disturbances, but to the natural variability or the successional processes occurring within those communities. Only communities dwelling in the rip-rap protection area were affected by the proximity of the discharges.  相似文献   
77.
Using the HyMap instrument, we have acquired visible and near infrared hyperspectral data over the Maqsad area of the Oman ophiolite (~ 15 × 60 km). This survey allowed us to identify and map the distribution of clinopyroxene-rich cumulates (inter-layered clinopyroxenites and wehrlites) whose occurrence was previously undocumented in this area. The cumulates reach several hundred meters in thickness and crop out at distances exceeding 15 km on both sides of the Maqsad former spreading centre. They occur either in mantle harzburgites, as km-sized layered intrusions surrounded by fields of pegmatitic dykes consisting of orthopyroxene-rich pyroxenite and gabbronorites, or at the base of the crustal section where they are conformably overlain by cumulate gabbros. These ultramafic cumulates crystallized from silica- and Mg-rich melts derived from a refractory mantle source (e.g. high Cr#, low [Al2O3], low [TiO2]). These melts are close to high-Ca boninites, although, strictly speaking, not perfect equivalents of present-day, supra-subduction zone, boninites. Chemical stratigraphy reveals cycles of replenishment, mixing and fractional crystallization from primitive (high Mg#) melts, typical of open magma chambers and migration of inter-cumulus melts. The TiO2 content of clinopyroxene is always low (≤ 0.2 wt.%) but quite variable compared to the associated pegmatites that are all derived from a source ultra-depleted in high field strength elements (HFSE). This variability is not caused by fractional crystallization alone, and is best explained by hybridization between the ultra-depleted melts (parent melts of the pegmatites) and the less depleted mid-ocean ridge basalts (MORB) parent of the dunitic–troctolitic–gabbroic cumulates making up the crustal section above the Maqsad diapir.We propose that, following a period of magma-starved spreading, the Maqsad mantle diapir, impregnated with tholeiitic melts of MORB affinity, reached shallow depths beneath the ocean ridge. This diapir induced melting of the formerly accreted and hydrothermally altered lithosphere. At this stage, these boninitic-like lithospheric melts crystallized as pegmatitic dykes. As the diapir continued to rise, the amount of MORB reaching shallow depths increased, together with the surrounding temperature, leading to the formation of magma chambers where the crystallization of layered cumulates became possible. These cumulates remained rich in pyroxene and devoid of plagioclase as long as the contribution of MORB-derived melts was moderate relative to the lithospheric-derived melts. As the contribution of MORB to the refilling of the magma chamber increased, gabbroic cumulates started to crystallize.  相似文献   
78.
Arsenic from natural and anthropogenic sources is a worldwide contaminant of aqueous environments, such as groundwater and soils. The present investigation was performed on Mexican soils contaminated with residues from metallurgical processes that have shown a natural As attenuation. Experimental aqueous arsenic extractions in these were successfully simulated for almost half of the soil samples using a database updated for all known metal arsenate formation constants, revealing the predominance of solubility-controlled As mobility via Pb, mixed Pb–Cu, and Ca arsenate solid formation. The relatively low total Fe/As ratios (2–13 w/w) present in the soils studied, together with the high and equivalent contents of As, Pb, and Cu in these, favor the precipitation process over As(V) adsorption to Fe oxides, despite a 2% average Fe content in the soils studied. Under these conditions bicarbonate was found to be a highly unsuitable extractant due to its indirect As release from the solid arsenates, via heavy metal carbonate precipitation processes.  相似文献   
79.
The 7-year-old mine tailings pile P2 from Concepción del Oro has been revegetated spontaneously by xerophyte grasses, covering about the 30% of its surface. To elucidate the effect of the grass cover in the geochemical behavior of the sulfide minerals (SM) and metals, the strata of four selected profiles (P2-I, P2-II, P2-III and P2-IV, with high, middle, low, and null grass cover, respectively) were analyzed mineralogically and chemically, using scanner electron microscopy, X-ray diffractometer and performing a six-step sequential extraction method. An older (50-year-old) and uncovered (without grass cover) profile of the tailings pile P3 was also analyzed. In all the profiles from P2, the SM oxidation is not yet an extended process; however, the samples from the uncovered profile P2-IV showed evidences of SM (pyrite and chalcocite) oxidation, as well as the presence of gypsum and Fe oxides, as the major secondary phases resulted from the SM oxidation. Additionally, the carbonate content and pH values in P2-IV were lower than in the covered profiles from P2. The oldest and uncovered P3-I profile showed an extensive oxidation of sulfurs which resulted in the depletion of carbonates and a pH 2. Another distinctive characteristics of the covered profiles was that Pb, Cu, and Zn were mainly associated with the reducible fractions (carbonates and/or amorphous oxides); meanwhile, in the uncovered (P2-IV and P3-I) such metals were mainly associated with the oxidizable fraction (crystalline oxides). The results suggest that the mineralogical transformations control metal stability in plant-covered impoundments (phytostabilization): the occurrence of a thick grass cover, with an efficient water usage and retention, seems to shun both the acidic dissolution of carbonates and the reductive dissociation of the formerly present oxyhydroxides, which is desired for remediation tasks. This is the first report about the effects of grass cover for a carbonaceous and unsaturated mine tailings from a semiarid region, that can help in a better understanding of the scope of phytoremediation in such conditions.  相似文献   
80.
Journal of Geographical Systems - In the past ten years, cities have experienced a burst of micromobility services as they offer a flexible transport option that allows users to cover short trips...  相似文献   
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